The main character was a brave boy.
Meaning: This means that the boy was the most important person in the story and he was also very courageous.
Choice of Words: Main means principal or most important. Character means a person in a story or play. Brave means having or showing courage. When you put them together, "main character" means the most important person in a story or play, and "brave boy" means a boy who has or shows courage.
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Related Expressions